Structure of Lipids (Supplement)

Lipids are made from glycerol and three fatty acid chains. This structure is called a triglyceride.

  • Each fatty acid joins to the glycerol by a condensation reaction, releasing one molecule of water. Three fatty acids = three water molecules released.
  • The bond formed between glycerol and a fatty acid is called an ester bond.
  • Saturated fats: no double bonds between carbon atoms in the fatty acid chains. Tend to be solid at room temperature (e.g. Butter, lard). Found mainly in animal products.
  • Unsaturated fats: one or more double bonds between carbons. Tend to be liquid at room temperature (oils, e.g. Olive oil, sunflower oil). Found mainly in plants and fish.

Biological Roles of Lipids

  • Energy storage: lipids release more than twice the energy per gram (37 kJ/g) compared to carbohydrates (17 kJ/g). They are stored under the skin and around organs.
  • Thermal insulation: a layer of subcutaneous fat beneath the skin reduces heat loss. Marine mammals like whales have thick blubber.
  • Protection: fat cushions organs like the kidneys and heart, protecting them from physical damage.
  • Cell membranes: phospholipids (modified lipids with a phosphate group) form the bilayer of cell membranes.
  • Waterproofing: waxy lipids on leaf surfaces (cuticle) reduce water loss by evaporation.
  • Buoyancy: fat is less dense than water, helping aquatic mammals float.

The Ethanol Emulsion Test for Lipids

  1. Crush or dissolve the food sample in ethanol (alcohol).
  2. Shake well to dissolve any lipids present.
  3. Pour the ethanol solution into a test tube of cold water.
  4. A cloudy white emulsion forms if lipids are present.
  5. If no lipids are present, the solution remains clear.

Why does this work? Lipids dissolve in ethanol but not in water. When the ethanol solution is added to water, the lipids come out of solution and form tiny droplets: creating the cloudy emulsion.